Evaluated Chemical Kinetic Data for the Reactions of Atomic Oxygen O(3P) with Unsaturated Hydrocarbons

Abstract

Chemical kinetic data for reactions of O(3P) atoms with unsaturated hydrocarbons are compiled and critically evaluated. Specifically, the reactions considered include the interactions of the ground electronic state of oxygen atoms, O(3P), with alkenes, cycloalkenes, halogen substituted alkenes and ketenes, alkynes, halogen substituted alkynes, aromatic hydrocarbons, halogen substituted aromatic hydrocarbons and pyridine. All kinetic data considered were restricted to gas phase reactions. ‘‘Recommended’’ values of the rate parameters have been assessed and conservative uncertainty limits assigned to them.