The effect of rapid neutral-neutral reactions on chemical models of dense interstellar clouds

Abstract
Recent experiments on rapid neutral–neutral reactions involving the radical CN at low temperature and the neutral C atom at room temperature suggest that atom–neutral and radical–neutral reactions may be generally more rapid at low temperature than hitherto thought. We have included a variety of rapid neutral–neutral reactions in our gas-phase chemical models of quiescent, dense interstellar clouds. We find the calculated abundances of many molecules to be greatly changed from previous values. In particular, the peak ‘early-time’ abundances of organic molecules are reduced.