Electron Spin Resonance of a Sigma-Electron Radical in X-Ray-Irradiated Malonamide
- 1 May 1969
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 50 (9), 3701-3706
- https://doi.org/10.1063/1.1671615
Abstract
Two radical species were formed when malonamide crystals were irradiated with x ray. One was a π‐electron radical of common occurrence, NH2COĊHCONH2, and the other was interpreted as a σ‐electron radical of the formula NH2COĊH2COṄH. The ESR spectra of the latter were studied in detail and the assignments were substantiated by ESR spectra of deuterated malonamide and 15N‐malonamide.Keywords
This publication has 20 references indexed in Scilit:
- Electron Spin Resonance of Irradiated Single Crystals of Sodium and Potassium 1-OximinopropionatesBulletin of the Chemical Society of Japan, 1967
- Electron spin resonance studies of oxidation. IX. Some interesting properties of iminoxy radicalsThe Journal of Physical Chemistry, 1967
- A STUDY BY ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY OF RADICALS FORMED FROM ACETAMIDE AND FORMAMIDECanadian Journal of Chemistry, 1966
- Electron Spin Resonance Analysis of a γ-Irradiated Single Crystal of PentafluoropropionamideThe Journal of Chemical Physics, 1966
- Anisotropic Hyperfine Structure in ESR Spectra: Applications to Irradiated Crystals of Malonamide and GlycineThe Journal of Chemical Physics, 1965
- ESR Study of Ethynyl and Vinyl Free RadicalsThe Journal of Chemical Physics, 1964
- ESR Spectrum and Structure of the Formyl RadicalThe Journal of Chemical Physics, 1962
- A Paramagnetic Species in Irradiated NaNO2The Journal of Chemical Physics, 1961
- Electron spin resonance and structure of the CO-2radical ionMolecular Physics, 1961
- Electron Spin Resonance in an Irradiated Single Crystal of DimethylglyoximeThe Journal of Chemical Physics, 1959