Routes to trans-Chrysanthemic Acid. I. Elaboration of (-)Dihydrochrysanthemclactone from (+)3-Carene
- 1 January 1980
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 10 (12), 921-927
- https://doi.org/10.1080/00397918008061852
Abstract
A popular synthetic target usually embodies unique structural features and/or implicates practical use. Chrysanthemic acid (1) which meets both criteria has indeed attracted enormous effort in its synthesis.1 From a utilitarian viewpoint, the total synthesis of trans-chrysanthemic acid is attended by the drawback of requiring optical resolution,2 because only the dextrorotatory antipode proves valuable for reconstitution of pyrethroid insecticides.Keywords
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