The Kinetics of the Oxidation of Isopropyl Alcohol by Chromic Acid
- 1 November 1943
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 11 (11), 506-512
- https://doi.org/10.1063/1.1723790
Abstract
The oxidation of isopropyl alcohol by chromic acid is a reaction first order with respect to the acid chromate ion, HCrO4−, first order with respect to the alcohol, and second order with respect to hydrogen ion. Evidence has been obtained that the reaction proceeds by way of a compound of tetravalent or of pentavalent chromium. On the basis of these facts, a mechanism for the oxidation has tentatively been suggested.Keywords
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