Structure in Ionic Solutions. III
- 1 December 1958
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 29 (6), 1371-1375
- https://doi.org/10.1063/1.1744725
Abstract
Measurements of x‐ray scattering from ferric chloride solution in the concentration range from 1.5M to 5M have been made. The radial distributions calculated from these measurements indicate a large degree of local ordering of the ions, with formation of Fe+3—Cl— complexes. At the highest concentration the [FeCl6]—3 ion appears to be the main species present. As the concentration is lowered the coordination of the Cl—s around Fe+3 becomes less definite and other species appear; in particular, the presence of Fe2Cl6 is indicated.This publication has 10 references indexed in Scilit:
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