Calculated Auger transition rates for HF
- 1 April 1979
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 19 (4), 1649-1655
- https://doi.org/10.1103/physreva.19.1649
Abstract
We report ab initio calculations of Auger transition rates for hydrogen fluoride, using Hartree-Fock molecular orbitals from finite-basis Slater-type-orbitals calculations. Continuum orbitals are calculated as spherical waves in the single-center expanded-molecular potential. Results show reasonable agreement with experiment and with previous calculations for neon. The effect of final-state configuration mixing is discussed, as well as the use of perturbation theory for improving the continuum orbitals.Keywords
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