Temperature- and Electrophile-Dependent Stereocontrol: A Structural and Mechanistic Investigation of (−)-Sparteine-Mediated Asymmetric Lithiation−Substitution Sequences of N-Boc-N-(p-Methoxyphenyl)cinnamylamine
- 29 September 1999
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 121 (41), 9522-9530
- https://doi.org/10.1021/ja9910560
Abstract
No abstract availableKeywords
This publication has 25 references indexed in Scilit:
- Reorientation Dynamics within Ion-Paired Allylic Lithium Compounds: Isolation of Inversion ProcessesThe Journal of Organic Chemistry, 1999
- Complex-Induced Proximity Effects: Stereoselective Carbon−Carbon Bond Formation in Chiral Auxiliary Mediated β-Lithiation−Substitution Sequences of β-Substituted Secondary CarboxamidesThe Journal of Organic Chemistry, 1998
- A Mechanistic and Structural Investigation of the (−)-Sparteine Mediated Asymmetric Benzylic Lithiation Substitution Reactions of N-Boc-N-(p-methoxyphenyl)benzylamineJournal of the American Chemical Society, 1997
- Ligand Control and Asymmetric Michael Reactions of Enantioenriched Configurationally Stable N-Boc Anilino Benzylic and Allylic Organolithium SpeciesJournal of the American Chemical Society, 1997
- Enantioselective transformations of configurationally labile α-phenylseleno-alkyllithium compoundsJournal of the Chemical Society, Perkin Transactions 2, 1993
- Stereochemical studies on chiral, nonconjugated, nitrogen-substituted carbanions generated by tin-lithium exchangeJournal of the American Chemical Society, 1991
- Preparation of an Enantiomerically Enriched Allyllithium Derivative by Deprotonation with Kinetic Resolution of EnantiomersAngewandte Chemie International Edition in English, 1990
- Dynamics of solvated lithium(+) within exo,exo-[1,3-bis(trimethylsilyl)allyl]lithium N,N,N',N'-tetramethylethylenediamine complexJournal of the American Chemical Society, 1990
- Asymmetric Homoaldol Reaction by Enantioselective Lithiation of a Prochiral 2‐Butenyl CarbamateAngewandte Chemie International Edition in English, 1989
- Remarks on the chameleon behavior of an allyllithium: carbon-13 and lithium-6 NMRThe Journal of Organic Chemistry, 1985