A reassessment of the isoinversion principle

1 January 1995

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 3,p. 357-358
https://doi.org/10.1039/c39950000357

Abstract

A maximum in a plot of In P vs. 1/T does not necessarily imply that the values of ΔΔH^‡ for the two possible rate determining steps are of opposite sign.

Keywords

REASSESSMENT
SIGN
PLOT
1/T
ΔΔH
OPPOSITE
STEPS
NECESSARILY
ISOINVERSION PRINCIPLE

Cited by 28 articles