Phase Transformation Studies in TiO2 Supporting Different Defect Mechanisms in Vacuum-Reduced and Hydrogen-Reduced Rutile
- 1 November 1964
- journal article
- research article
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 35 (11), 3414-3416
- https://doi.org/10.1063/1.1713231
Abstract
Studies of the anatase‐rutile transformation show that the rate of transformation is accelerated in hydrogen atmospheres and retarded in vacuum. This information, interpreted in terms of the defect structure of TiO2, supports data obtained by other investigators indicating that the mechanism by which nonstoichiometric rutile is formed depends upon the atmosphere in which reduction occurs.Keywords
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