THE REACTION OF tert-BUTOXY RADICALS WITH 2,6-Di-tert-BUTYL-4-METHYLPHENOL AND 2,6-Di-tert-BUTYLPHENOL
- 1 November 1963
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 41 (11), 2807-2815
- https://doi.org/10.1139/v63-412
Abstract
The products of the reaction of t-butoxy radicals with 2,6-di-t-butyl-4-methylphenol and 2,6-di-t-butylphenol in carbon tetrachloride have been analyzed quantitatively. There is a satisfactory agreement between the measured and calculated yields of t-butanol with both phenols. The deuterium isotope effect (kh/kd) for abstraction of the phenolic hydrogen from 2,6-di-t-butyl-4-methylphenol is about 6.4.Keywords
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