Synthesis and characterization of "face-to-face" porphyrins.
- 1 January 1977
- journal article
- research article
- Published by Proceedings of the National Academy of Sciences in Proceedings of the National Academy of Sciences
- Vol. 74 (1), 18-22
- https://doi.org/10.1073/pnas.74.1.18
Abstract
The syntheses of four binary porphyrins, two of which are constrained to a "face-to-face" conformation, and their Co2+ and Cu2+ derivatives are described. Electron spin resonance indicates that the intermetallic separation in the binuclear "face-to-face" porphyrins is about 6.5-6.8 A. Electronic spectra and proton magnetic resonance spectra support the postulated "face-to-face" conformations. A hypothesis that related compounds may serve as multielectron redox catalysts for O2 and N2 is presented.This publication has 6 references indexed in Scilit:
- Organic dyestuffs as catalysts for fuel cellsPublished by Springer Nature ,2006
- The nitrogen-fixing complex of bacteriaBiochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, 1975
- Picket fence porphyrins. Synthetic models for oxygen binding hemoproteinsJournal of the American Chemical Society, 1975
- Moessbauer spectroscopic evidence for the electronic configuration of iron in horseradish peroxidase and its peroxide derivativesBiochemistry, 1969
- The Reaction of Reduced Cytochrome c Oxidase with OxygenJournal of Biological Chemistry, 1967
- An Electron Spin Resonance Study of Copper Uroporphyrin III and Other Touraco Feather ComponentsJournal of Biological Chemistry, 1965