Study of the Isothermal Bulk Copolymerization of Acrylic and Methacrylic Acid Esters
- 1 May 1983
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 19 (7), 987-997
- https://doi.org/10.1080/00222338308081079
Abstract
The course and kinetics of the isothermal bulk polymerization of ethyl acrylate, 2-ethylhexyl acrylate, and methyl methacrylate and their copolymerization in different mol ratios were studied by differential scanning calorimetry at 363 K. The initiator used was 2,2′-azoisobutyronitrile. The courses of reaction, the copolymerization enthalpies, the copolymerization parameters, and the specific constants of the rate of polymerization were determined.Keywords
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