The 90° yield of the D(3He, γ)5Li reaction has been measured from 2.3 to 11.2 MeV 3He energy. No clear evidence of a level in 5Li has been found over this energy range. The upper limits for the resonance integrated cross section and gamma-ray width were estimated to be σint ~ 15 μb MeV and Γγ ~ 100eV, respectively.