Interactions of H— Ions and H Atoms with Ne, A, and H2
- 1 June 1958
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 28 (6), 1070-1074
- https://doi.org/10.1063/1.1744345
Abstract
Previous work on the systems H—–He and H–He serves as a model for the calculation of the interactions of H— ions and H atoms with Ne, A, and H2 from an analysis of beam scattering measurements. It is shown that a mutually consistent interpretation can be developed on the assumption that the forces are repulsive in the region of interest. The H— ion elastic scattering cross sections are used to calculate the interactions of H— with Ne, A, and H2, and the electron detachment cross sections are used to locate the points at which these potential energy curves cross the corresponding curves for H atoms. The crossing points are shown to be consistent with potential energy curves for the interactions of H atoms with Ne, A, and H2 obtained directly or indirectly from independent scattering measurements involving beams of H atoms. The crossing points are used to extend these potential energy curves over a wider range of validity than previously available. Such a mutually consistent picture does not seem to emerge when attractive forces are assumed for the H— interactions.Keywords
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