Crystallization Process from Amorphous PbTiO3
- 1 May 1980
- journal article
- Published by IOP Publishing in Japanese Journal of Applied Physics
- Vol. 19 (5), L255-258
- https://doi.org/10.1143/jjap.19.l255
Abstract
Investigation has been made of the crystallization from the rapidly quenched amorphous state of PbTiO3 utilizing DTA and Raman spectroscopy. The DTA curves reveal sharp exothermic peaks between 500 and 600°C on heating the as-quenched samples. Essential differences between the Raman spectra from the as-quenched state and those from the crystalline state have been recognized: the soft mode observed in the crystalline state is found not to exist in the as-quenched state. By annealing samples, a dramatic change in the Raman spectra due to the structural relaxation is clearly visible.Keywords
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