Catalytic Enantioselective O−H Insertion Reactions
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- 21 March 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (14), 4594-4595
- https://doi.org/10.1021/ja0607739
Abstract
The first effective method for catalytic enantioselective insertions into O−H bonds has been developed. Specifically, a copper/bisazaferrocene catalyst couples alcohols such as 2-trimethylsilylethanol with α-aryl-α-diazo esters in high yield and good ee.Keywords
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