Rearrangement of 14β-Hydroxy-12β-sulfoxy-steroids to 13,17-Seco-12,17-cyclo-steroids; a 2D-NMR Analysis
Open Access
- 1 May 1985
- journal article
- research article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 40 (5), 656-660
- https://doi.org/10.1515/znb-1985-0516
Abstract
The rearrangement of 3-oxo-14.beta.-hydroxy-12.beta.-methanesulfoxy-card-20(22)-enolide and 14.beta.-hydroxy-12.beta.-methanesulfoxy-pregnane-3,20-dione during elimnation of the sulfoxygroups was studied. By means of 2D[2-dimensional]-NMR analysis the structures were determined as 13,17-seco-12,17-cyclo-steroids.This publication has 1 reference indexed in Scilit:
- Studies on C-nor-D-homsteroids—IXTetrahedron, 1968