INTENSITY IN THE RAMAN EFFECT: IV. RAMAN INTENSITY SUM RULES AND FREQUENCY ASSIGNMENTS FOR CH3CN, CD3CN, CH3CCl3, AND CD3CCl3

Abstract

The standard intensities of the Raman bands of CH₃CN, CD₃CN, CH₃CCl₃ and CD₃CCl₃ have been obtained for the liquids with a photoelectric, grating spectrometer. The intensity sum rules for isotopic homologues are valid within the experimental error. The infrared spectra of CD₃CN and CD₃CCl₃ have been obtained in the liquid phase and in the vapor phase. A definitive assignment of v₁₁(e) has been made for methyl chloroform.