Unexpected reactions of pentafluorophenylboron compounds with η-cyclopentadienyl(benzamidinato)zirconium derivatives
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 2607-2608
- https://doi.org/10.1039/c39940002607
Abstract
The new base-free compounds [{Zr(η-C5R5)[η-CPh{N(SiMe3)}2]Cl}][B(C6F5)3X]2(R = H, X = Me, CH2Ph or R = Me, X = C6F5*) and [{(η-C5H5)[η-CPh{N(SiMe3)}2](C6F5)}Zr(µ-Me)B(C6F5)3}],* are prepared; the formation of the latter requires the transfer of a C6F5 group from [B(C6F5)4]:* indicates the crystal structure has been determined.Keywords
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