Infrared Spectroscopic Study of the Photolysis of Methyl Azide and Methyl-d3 Azide in Solid Argon and Carbon Dioxide
- 1 October 1961
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 35 (4), 1491-1497
- https://doi.org/10.1063/1.1732070
Abstract
Experiments have been carried out on the photolysis of methyl azide and methyl‐d3 azide at high dilution in solid argon (4.2°K) and carbon dioxide (∼50°K). Photolysis of these species in argon and carbon dioxide matrices results in the appearance of a number of new spectral features in the 3300–600 cm—1 region. The spectroscopic data for the photolysis products appear to be consistent with the identification of these species as methyleneimine (CH2=NH) and methyleneimine‐d3 (CD2=ND).Keywords
This publication has 9 references indexed in Scilit:
- The Methyl Imino RadicalThe Journal of Physical Chemistry, 1957
- Solid State Anomalies in Infrared SpectroscopyThe Journal of Physical Chemistry, 1957
- Spectroscopic Studies of Reactive Molecules by the Matrix Isolation MethodThe Journal of Chemical Physics, 1956
- Infrarotuntersuchungen an Oximen II.Zeitschrift für Physikalische Chemie, 1956
- Ketimines. VIII. Infrared Spectra of KetiminesJournal of the American Chemical Society, 1954
- The Vibrational Frequencies of EthyleneThe Journal of Chemical Physics, 1950
- The Thermal Decomposition of Methyl Azide. A Homogeneous Unimolecular ReactionJournal of the American Chemical Society, 1933
- THE QUANTUM YIELD IN THE PHOTOCHEMICAL DECOMPOSITION OF HYDROGEN AZIDEJournal of the American Chemical Society, 1930
- THE PRODUCTS OF THE PHOTOCHEMICAL DECOMPOSITION OF HYDROGEN AZIDEJournal of the American Chemical Society, 1928