Ambient Temperature, Tandem Catalytic Dehydrocoupling−Hydrogenation Reactions Using Rh Colloids and Me2NH·BH3 as a Stoichiometric H2 Source
- 13 February 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (9), 2698-2699
- https://doi.org/10.1021/ja039696x
Abstract
Highly active Rh colloids, generated in situ during the catalytic dehydrocoupling of Me2NH·BH3 using [{Rh(cod)(μ-Cl)}2] as a precatalyst, are capable of efficiently hydrogenating alkenes at 25 °C in a one-pot procedure using only the evolved H2 from the initial dehydrocoupling reaction.Keywords
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