EFFECT OF FLUCTUATIONS OF FREE RADICAL CONCENTRATIONS ON THE CALCULATION OF RELATIVE RATE CONSTANTS
- 1 February 1954
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 32 (2), 63-70
- https://doi.org/10.1139/v54-011
Abstract
The effect of fluctuations in free radical concentrations on the values of relative reaction rate constants calculated from steady state expressions has been evaluated for a number of idealized model cases, representative of various conditions usually encountered in experiments.Keywords
This publication has 3 references indexed in Scilit:
- Reaction of Methyl Radicals with Hydrogen and Deuterium1,2Journal of the American Chemical Society, 1952
- Wall Effects in Photochemically Induced Chain ReactionsJournal of the American Chemical Society, 1951
- The Effect of Intermittent Light on a Chain Reaction with Bimolecular and Unimolecular Chain-Breaking StepsThe Journal of Chemical Physics, 1942