C−H and C−C Bond Activation of Primary Amines through Dehydrogenation and Transimination
- 15 February 2001
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 3 (5), 785-787
- https://doi.org/10.1021/ol015563+
Abstract
Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C−H bond activation, ortho-alkylation, and C−C bond activation to afford a variety of ketones in the reaction of 1-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline.Keywords
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