III. Experiments on the depolarisation of light as exhibited by various mineral, animal, and vegetable bodies, with a reference of the phenomena to the general principles of polarisation. By David Brewster, LL. D. F. R. S. Edin and F. S. A. Edin. In a letter addressed to the Right Hon. Sir Joseph Banks, Bart. K. B. P. R. S
Dear Sir Towards the end of the year 1812, when I was engaged in examining the light transmitted through diaphanous bodies, I discovered the property which many of them possessed of depolarising the rays of light, or of depriving them of the polarity which they had received, either by reflection from the surface of a transparent body, or by transmission through a plate of agate. A short account of these experiments, which were exhibited to many of my friends in Edinburgh, was soon afterwards published in my treatise on new philosophical instruments. As this singular property was possessed by numerous substances that exhibited no marks of double refraction, and even by animal and vegetable products, such as horn, tortoise shell, and gum Arabic, it appeared necessary to distinguish it by a new name, and to refer it to a species of crystallization different from that of doubly refracting crystals. The circumstance, however, of agate and Iceland spar possessing the faculty both of polarising and depolarising light, and the constant relation in the position of the axes which regulated these apparently opposite actions, induced me to think that the two classes of phenomena had the same origin. This opinion was afterwards strengthened by an experiment with a bundle of glass plates, in which light was depolarised by polarising it in a new plane; but in applying the principle to other phenomena, I was baffled in every attempt to generalise them. By extending, however, and varying the experiments; by examining the optical properties of every substance which I could command, and by comparing their structure with the phenomena which they exhibited, I have been led to the general principle to which they all belong, and to a series of results which, from their very nature, could not easily have been established by direct experiment. These conclusions, independently of their optical consequences, are peculiarly interesting to the chemist and the natural philosopher, by disclosing the structure of organised substances, and exhibiting new relations among the bodies of the animal, the vegetable, and the mineral kingdoms.