[Ru6(CO)18]2? in NaX zeolite cages: characterization by EXAFS and FTIR spectroscopy

1 January 1995

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 5,p. 507-508
https://doi.org/10.1039/c39950000507

Abstract

Ru^III(NH₃)₆ in the cages of NaX zeolite is converted in the presence of CO + H₂ into [Ru₆(CO)₁₈]^2–, which is reversibly fragmented and reconstructed under oxidative and reductive conditions, respectively.

Keywords

FTIR SPECTROSCOPY

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