A homochiral triple helix constructed from an axially chiral bipyridineElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b212781d/

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Abstract
A homochiral triple helix was self-assembled from an axially chiral bipyridine and a linear metal-connecting point, which further assembles into a 2D network via infinite π⋯π stacking interactions and acts as a host for the inclusion of guest molecules.