Highly Enantioselective 1,2-Addition of Lithium Acetylide-Ephedrate Complexes: Spectroscopic Evidence for Reaction Proceeding via a 2:2 Tetramer, and X-ray Characterization of Related Complexes
- 28 October 2000
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 122 (45), 11212-11218
- https://doi.org/10.1021/ja0022728
Abstract
No abstract availableKeywords
This publication has 14 references indexed in Scilit:
- Practical Asymmetric Synthesis of Efavirenz (DMP 266), an HIV-1 Reverse Transcriptase InhibitorThe Journal of Organic Chemistry, 1998
- Lithium Ephedrate-Mediated Addition of a Lithium Acetylide to a Ketone: Solution Structures and Relative Reactivities of Mixed Aggregates Underlying the High EnantioselectivitiesJournal of the American Chemical Society, 1998
- Alkali Metal Cation π-Interactions in Metalated and Nonmetalated Acetylenes: π-Bonded Lithiums in the X-ray Crystal Structures of [Li−C⋮C−SiMe2−C6H4−OMe]6and [Li−O−CMe2−C⋮C−H]6and Computational StudiesJournal of the American Chemical Society, 1997
- Preparation of methyl carbamates via a modified Hofmann rearrangementTetrahedron Letters, 1997
- Syntheses of Two Stereoselectively Trideuterated VinylcyclopropanesThe Journal of Organic Chemistry, 1995
- Asymmetric .alpha.-amination of ketone enolates by chiral .alpha.-chloro-.alpha.-nitroso reagents: a new approach to optically pure erythro-.beta.-amino alcoholsJournal of the American Chemical Society, 1992
- Reactions of metal-metal multiple bonds. 10. Reactions of Mo2(OR)6 (M.tplbond.M) and [Mo(OR)4]x compounds with molecular oxygen. Preparation and characterization of oxo alkoxides of molybdenum: MoO2(OR)2, MoO2(OR)2(bpy), MoO(OR)4, Mo3O(OR)10, Mo4O8(OR)4(py)4, and Mo6O10(OR)12Inorganic Chemistry, 1984
- The unusual structures, energies, and bonding of lithium-substituted allenes, propynes, and cyclopropenesJournal of the American Chemical Society, 1979
- Lithium Bis(trimethylsilyl)amide and Tris(trimethylsilyl)amineInorganic Syntheses, 1966
- A New Synthesis of 1,1-Dibromoölefins via Phosphine-Dibromomethylenes. the Reaction of Triphenylphosphine with Carbon TetrabromideJournal of the American Chemical Society, 1962