Variational Perturbation Method Based on the Principle of Moments
- 5 March 1968
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 167 (1), 112-115
- https://doi.org/10.1103/physrev.167.112
Abstract
A simple practical variational perturbation method based on the approximate calculation of the moments of the resolvent operator is developed. The method has been applied to the state of the helium atom. The trial wave functions have been expanded in terms of naturally spaced groups of Hylleraas functions up to 95 terms. The 95 term trial function gives an upper bound of -2.903724305 atomic units to the ground-state energy. Other numerical results have been compared with the 21st-order perturbation energies of Midtdal and other previous calculations. It is found that comparable results can be obtained by the present simple calculation.
Keywords
This publication has 10 references indexed in Scilit:
- Perturbation Method Based on the Principle of MomentsPhysical Review B, 1966
- Perturbation-Theory Expansions Through 21st Order of the Nonrelativistic Energies of the Two-Electron SystemsandPhysical Review B, 1965
- Two-Electron Atoms III. A Sixth-Order Perturbation Study of theGround StateReviews of Modern Physics, 1963
- Ground-State Energy of the NucleonPhysical Review B, 1962
- andStates of HeliumPhysical Review B, 1959
- The physical nucleon in static source meson theoryAnnals of Physics, 1959
- Meson kinematics in static source meson theoriesAnnals of Physics, 1959
- Convergence of the Method of MomentsPhysical Review B, 1958
- Method of Moments in Quantum MechanicsPhysical Review B, 1957
- Twenty-Parameter Eigenfunctions and Energy Values of the Ground States of He and He-Like IonsPhysical Review B, 1957