Terminal distributions of rotational energy in free jets of CO2 by infrared emission spectrometry
- 1 September 1982
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 77 (5), 2599-2606
- https://doi.org/10.1063/1.444134
Abstract
By means of Fourier transform infrared spectrometry we have analyzed the radiation from supersonic free jets of CO2 issuing from heated nozzle sources. The terminal rotational energy contents deduced from the spectra are consistent with those obtained by other methods. The distributions of this energy are clearly non‐Boltzmann. A two‐temperature model provides remarkably faithful descriptions of the observed distributions and leads to a simple characterization of the departure from rotational equilibrium in terms of a rotational entrophy. The results show that the extent of thls departure increases with increasing source density. Competition between rotation‐rotation and rotation‐translation exchanges seems to provide a plausible explanation for the observed behavior.Keywords
This publication has 24 references indexed in Scilit:
- Molecular beam magnetic resonance study of intra- and inter- molecular effects in H2in high rotational statesMolecular Physics, 1978
- Freezing of vibrational degrees of freedom in free-jet flows with application to jets containing CO2The Journal of Chemical Physics, 1975
- Relaxation rates from time of flight analysis of molecular beamsThe Journal of Chemical Physics, 1974
- Electric Resonance Spectroscopy of Hypersonic Molecular BeamsThe Journal of Chemical Physics, 1972
- Study of Relaxation in Free Jets Using Temperature Dependence of n-Butane Mass SpectraThe Journal of Chemical Physics, 1972
- Rotational Relaxation of Molecular NitrogenThe Journal of Chemical Physics, 1967
- Measurements of Rotational Temperatures in a Low Density Wind TunnelPhysics of Fluids, 1966
- Velocity Distributions in Molecular Beams from Nozzle SourcesPhysics of Fluids, 1965
- Static Temperature Measurements in a Flowing GasPhysics of Fluids, 1962
- Geschwindigkeitsanalyse vonLaval-StrahlenThe European Physical Journal A, 1956