Selective Reduction of Conjugated Ethylenic Linkage in the Presence of Ion-Exchange Resin Bound Borohydride
- 1 June 1987
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 17 (8), 1007-1013
- https://doi.org/10.1080/00397918708063961
Abstract
The use of crosslinked polystyrene anion-exchange resin as a support for borohydride ions made it possible to reduce conjugated olefinic bonds selectively under very mild conditions. The isolation of the reduced products by a simple filtration and evaporation process is another interesting feature of this reaction.Keywords
This publication has 10 references indexed in Scilit:
- Methylcopper(I)-catalyzed selective conjugate reduction of .alpha.,.beta.-unsaturated carbonyl compounds by di-iso-butylaluminum hydride in the presence of hexamethylphosphoric triamideThe Journal of Organic Chemistry, 1986
- Palladium-catalyzed conjugate reduction of α-β-unsaturated carbonyl compound with tributyltin hydride. The promoting influence of the presence of protonic or lewis acids.Tetrahedron Letters, 1982
- Stereochemistry of 1,4-addition of nucleophiles to ethyl cyclohexylidenecyanoacetatesThe Journal of Organic Chemistry, 1982
- Knoevenagel-kondensationen mit TiCl4/base—IIITetrahedron, 1973
- Reduction of Conjugated Double Bonds with Sodium BorohydrideThe Journal of Organic Chemistry, 1966
- Reduction of Alkylidenecyanoacetates with Sodium BorohydrideThe Journal of Organic Chemistry, 1965
- 2-Amino-5,6-dihydro-1,3-oxazines. The Reduction of Carboxylic Esters with Sodium Borohydride1The Journal of Organic Chemistry, 1963
- ETHYL BENZALMALONATEOrganic Syntheses, 1945
- Condensation Reactions. II. Alkylidene Cyanoacetic and Malonic EstersJournal of the American Chemical Society, 1941
- The Introduction of Substituted Vinyl Groups. I. Isopropenyl Alkyl Malonic EstersJournal of the American Chemical Society, 1938