Détermination de la viscosité intrinsèque de solutions de polymères par une simple détermination de la viscosité

Abstract

By studying the molecular weights of various solutions of cis‐1,4‐polyisoprene the authors arrived at the formula \documentclass{article}\pagestyle{empty}$$\left[ \eta \right] = \sqrt {2/c} \sqrt {\eta _{sp} - {\rm l}n\eta } _{rel} $$ which allowed the calculation of the intrinsic viscosity of the polymer solutions by a single viscosity determination. The formula was verified for different systems of polymer–solvent and the values are in accord with those obtained by extrapolation. An operating concentration of about 0.2% is recommended.