Isotopically sensitive branching in the formation of cyclic monoterpenes: proof that (-)-.alpha.-pinene and (-)-.beta.-pinene are synthesized by the same monoterpene cyclase via deprotonation of a common intermediate
- 25 August 1987
- journal article
- research article
- Published by American Chemical Society (ACS) in Biochemistry
- Vol. 26 (17), 5383-5389
- https://doi.org/10.1021/bi00391a025
Abstract
Note: In lieu of an abstract, this is the article's first page.This publication has 4 references indexed in Scilit:
- Measurement of deuterium kinetic isotope effects in organic and biochemical reactions by natural abundance deuterium NMR spectroscopyJournal of the American Chemical Society, 1986
- Monoterpene cyclases: Use of the noncyclizable substrate analog 6,7-dihydrogeranyl pyrophosphate to uncouple the isomerization step of the coupled isomerization-cyclization reactionArchives of Biochemistry and Biophysics, 1986
- Stereochemistry at C-1 of geranyl pyrophosphate and neryl pyrophosphate in the cyclization to (+)- and (-)-bornyl pyrophosphate.Journal of Biological Chemistry, 1985
- BIOSYNTHESIS OF (+/-)-ALPHA-PINENE AND (-)-BETA-PINENE FROM GERANYL PYROPHOSPHATE BY A SOLUBLE ENZYME-SYSTEM FROM SAGE (SALVIA-OFFICINALIS)1982