Catalytic Enantioselective [2 + 4] and [2 + 2] Cycloaddition Reactions with Propiolamides
- 22 May 2008
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 130 (24), 7532-7533
- https://doi.org/10.1021/ja8015318
Abstract
We report here the catalytic and highly enantioselective [2 + 4] and [2 + 2] cycloaddition reactions of electron-rich dienes or silyl enol ethers with electron-deficient propiolamide derivatives induced by copper(II)•3-(2-naphthyl)-l-alanine amide complex.Keywords
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