Spin-State Transformation in Some Iron(III) Complexes with Schiff Base Ligands
- 1 May 1988
- journal article
- research article
- Published by Taylor & Francis in Comments on Inorganic Chemistry
- Vol. 7 (1), 41-52
- https://doi.org/10.1080/02603598808072298
Abstract
The magnetic properties of spin-crossover iron(III) complexes with N402 ligands are reviewed and especially the rapid spin-state interexchange is discussed on the basis of absorption, ir, epr and Mössbauer spectra. Results from single crystal X-ray structure determination, kinetics and dilution experiments are also reported.Keywords
This publication has 28 references indexed in Scilit:
- Rapid electronic relaxation between S = 3/2 and S = 1/2 states in (N,N'-o-phenylenebis(salicylideneaminato))nitrosyliron, [Fe(salphen)NO]Inorganic Chemistry, 1987
- New spin-crossover iron(III) complexes with large hysteresis effects and time dependence of their magnetismJ. Chem. Soc., Dalton Trans., 1987
- Dynamics of spin-state interconversion and cooperativity for ferric spin-crossover complexes in the solid state. 6. Magnetic and spectroscopic characterizations of [Fe(3-OEt-SalAPA)2]X (X = ClO4-, or BPh4-)Inorganic Chemistry, 1986
- Spectroscopic and magnetic properties of [FeL2(salacen)]PF6(L = imidazole or N-methylimidazole): new examples of intermediate electronic relaxation between S=½ and S=52 states. X-Ray crystal structure of [Fe(Him)2(salacen)]PF6J. Chem. Soc., Dalton Trans., 1986
- Dynamics of spin-state interconversion and cooperativity for ferric spin-crossover complexes in the solid state. 2. Perturbations of the fast spin-flipping N4O2 complex [Fe(SalAPA)2]ClO4Inorganic Chemistry, 1984
- Synthesis and Characterization of Iron(III) Complexes with Unsymmetrical Quadridentate Schiff Bases, and Spin Equilibrium Behavior in SolutionBulletin of the Chemical Society of Japan, 1984
- Rapid electronic relaxation phenomenon in a 2T .dblarw. 6A spin-equilibrium systemInorganic Chemistry, 1983
- Nature of the continuous high-spin (5T2) .dblharw. low-spin (1A1) transition in bis[2-[(4-methyl-2-pyridyl)amino]-4-(2-pyridyl)thiazole]iron(II) diperchlorate dihydrate and bis(tetrafluoroborate) dihydrate: Moessbauer effect and x-ray diffraction studyInorganic Chemistry, 1983
- A CHELATE RING SIZE EFFECT ON SPIN STATES OF IRON(III) COMPLEXES WITH HEXADENTATE LIGANDS DERIVED FROM SALICYLALDEHYDE AND 4,8-DIAZAUNDECANE-1,11-DIAMINE(3,3,3-tet) OR 4,7-DIAZADECANE-1,10-DIAMINE(3,2,3-tet), AND THEIR X-RAY STRUCTURESChemistry Letters, 1983
- Über die magnetische Susceptibilität der komplexen VerbindungenBerichte der deutschen chemischen Gesellschaft (A and B Series), 1931