A hexanuclear copper arylselenolate: synthesis, structure and proposal for its rearrangement
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 1011-1012
- https://doi.org/10.1039/c39950001011
Abstract
Copper(I) oxide reacts with selenol 2,4,6-Pri 3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate {Cu[Se(2,4,6-Pri 3C6H2)]}6 of 6, the solid state structure of which consists of a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.This publication has 18 references indexed in Scilit:
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