Dielectric Properties of Hydrogen Halides. II. Hydrogen Chloride
- 1 February 1954
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 22 (2), 284-288
- https://doi.org/10.1063/1.1740053
Abstract
Dielectric constant and loss measurements have been made for liquid and solid hydrogen chloride in the temperature range 63—190°K and frequency range 20 cps to 106 cps. The dielectric constants of the liquid and disordered solid phase stable above 99°K are described quite accurately by Onsager's equation. Below 99°K a slight dispersion with activation energy of 2.6 kcal/mole is found with dielectric constants in the range 3.7—4.3. Special precautions against sample inhomogeneity were necessary; these and various residual effects are discussed.Keywords
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