Observation of Dipole-Bound States of Negative Ions

Abstract
High-resolution threshold photodetachment of H2C-CHO has resulted in the observation of ∼50 narrow resonances (some <20 MHz full width at half maximum). These resonances are due to autodetachment from a diffuse negative-ion complex consisting of an electron weakly bound (∼5 cm1) by the dipolar electric field of the neutral. Electric fields of < 70 V/cm are adequate to detach the electron from the lower (bound) levels where autodetachment is not possible. Such states should exist for all neutrals with dipole moments greater than about 2 D.