Zur Kenntnis der Schlangengifte

Abstract
Cobra venom may be inactivated by NaHSO3 at pH 4.5 and by H2SO3 at pH 2. For comparison, the action of H2SO3 on other compounds containing cystine groups, such as l-cystine, S-S-glutathione, egg albumin and insulin, was studied. Cysteine-sulfo acid was obtained by dissolving 3.0 g. of 1-cystine in 1 L.H2O and by introducing SO2. After 72 hrs., the mixture was conc. acidified with H2SO4, and cysteinesulfo acid (C3H7O5NS2) obtained, m.p. 184o-185o. Upon hydrolysis with HC1 and acetic acid, the cysteinesulfo acid gave H2SO4 and cysteine. When treated with H2SO3 in a similar manner, cobra venom neurotoxin formed a product insoluble in H2O and one soluble in H2O. When hydrolyzed, these products gave H2SO3 and H2SO4. Under similar conditions, egg albumin, insulin and a protein obtained from Antiaris toxicara gave only H2SO4. The poisonous property of snake venom is possibly due to the presence of a prosthetic group in the molecule.