Carbon–carbon activation by rhodium in solution; sp2–sp3is preferred over sp3–sp3bond cleavage
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1965-1966
- https://doi.org/10.1039/c39950001965
Abstract
Reaction of the ethyl-aromatic phosphine 1 with PhRh(PPh3)3 results in C–H activation, yielding complex 2, which upon treatment with H2 undergoes selective cleavage of the sp2–sp3 hybridized C–C bond forming ethane and complex 3; Ar–C cleavage is also observed upon reaction of 1 with H2 and [RhCl(C8H14)2]2.Keywords
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