Tannins and related compounds. Part 13. Isolation and structures of trimeric, tetrameric, and pentameric proanthicyanidins from cinnamon
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 9,p. 2139-2145
- https://doi.org/10.1039/p19830002139
Abstract
A proanthocyanidin trimer, two tetramers, and a pentamer have been isolated in their free phenolic forms from cinnamon, the bark of Cinnamomum zeylanicum(Lauraceae). Partial acid-catalysed degradation of these tannins with phenylmethanethiol, in conjunction with 1H- and 13C-n.m.r. analysis, has unequivocally established their structures as epicatechin-(4β→8, 2β→7) epicatechin-(4α→8)-epicatechin (5); epicatechin-(4β→8, 2β→7)-epicatechin-(4α→8)-epicatechin (6); epicatechin-(4β→6)-epicatechin-(4β→, 2β→7)-epicatechin-(4α→8)-epicatechin (7); and epicatechin-(4β→8)-epicatechin-(4β→8)epicatechin-(4β→8, 2β→7)-epicatechin-(4α→8)-epicatechin (8).This publication has 1 reference indexed in Scilit: