Multifunctional Fourfold Interpenetrating Diamondoid Network: Gas Separation and Fabrication of Palladium Nanoparticles
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- 18 April 2008
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 14 (13), 3961-3967
- https://doi.org/10.1002/chem.200701813
Abstract
A fourfold interpenetrating diamondoid network, [{[Ni(cyclam)]2(mtb)}n]⋅8n H2O⋅4n DMF (1) (MTB=methanetetrabenzoate, DMF=dimethylformamide), has been assembled from [Ni(cyclam)][ClO4]2 (cyclam=1,4,8,11‐tetraazacyclotetradecane) and methanetetrabenzoic acid (H4MTB) in DMF/H2O (7:3, v/v) in the presence of triethylamine (TEA). Despite the high‐fold interpenetration, 1 generates 1D channels that are occupied by water and DMF guest molecules. Solid 1, after removal of guest molecules, exhibits selective gas adsorption behavior for H2, CO2, and O2 rather than N2 and CH4, suggesting possible applications in gas separation technologies. In addition, solid 1 can be applied in the fabrication of small Pd (2.0±0.6 nm) nanoparticles without any extra reducing or capping agent because a NiII macrocyclic species incorporated in 1 reduces PdII ions to Pd0 on immersion of 1 in the solution of Pd(NO3)2⋅2 H2O in MeCN at room temperature.Keywords
This publication has 67 references indexed in Scilit:
- TCNQ Dianion-Based Coordination Polymer Whose Open Framework Shows Charge-Transfer Type Guest InclusionJournal of the American Chemical Society, 2006
- Pd Nanoparticle Aging and Its Implications in the Suzuki Cross-Coupling ReactionLangmuir, 2005
- Redox‐Active Porous Metal–Organic Framework Producing Silver Nanoparticles from AgI Ions at Room TemperatureAngewandte Chemie, 2005
- Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound Cu3(BTC)2Microporous and Mesoporous Materials, 2004
- Nanopore Structure and Sorption Properties of Cu−BTC Metal−Organic FrameworkNano Letters, 2003
- Nickel(II) Macrocyclic Complexes with Long Alkyl Pendant Chain: Synthesis, X-ray Structure, and Anion Exchange Property in the Solid StateInorganic Chemistry, 2003
- Preparation of polychrome silver nanoparticles in different solventsJournal of Materials Chemistry, 2002
- Conduction electron paramagnetic resonance of metal nanoparticles in AlMCM-41 aluminosilica mesoporous molecular sievesPhysical Chemistry Chemical Physics, 2001
- 13C‐ENDOR Investigation of an Organic Tetraradical in the Quintet State; Synthesis of a Fourfold 13C‐Labeled TetrakisgalvinolAngewandte Chemie International Edition in English, 1986
- 13C-ENDOR-Untersuchung eines organischen Tetraradikals im Quintettzustand; Synthese eines vierfach13C-markierten TetrakisgalvinolsAngewandte Chemie, 1986