[60]Fullerene and TCNQ donor–acceptor crystals of octakis(dimethylamino) porphyrazine
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1703-1704
- https://doi.org/10.1039/c39950001703
Abstract
Reaction of octakis(dimethylamino) porphyrazine 1 with [60]fullerene gives a crystalline 2:1 charge-transfer (CT) complex as a three-dimensional network of chains; in contrast, reaction of 1 with tetracyanoquinodimethane (TCNQ) gives a crystalline 1:1 charge transfer salt as one-dimensional integrated stacks.Keywords
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