Cluster Expansions for Correlated Wave Functions of Finite Systems

Abstract

A theory of correlated wave functions for finite systems is developed which systematically neglects the contribution from three-body cluster terms. The approximation made leads to a derivation of a Bethe-Goldstone equation for finite systems which includes modified occupation probabilities and self-consistent potentials for occupied states. The absence of potentials in unoccupied states follows from the neglect of three-body cluster terms. It is also shown that a careful treatment of the Pauli principle and occupation probabilities allows the application of variational techniques.