Heats of mixing
- 1 January 1961
- journal article
- Published by Walter de Gruyter GmbH
- Vol. 2 (1-2), 141-146
- https://doi.org/10.1351/pac196102010141
Abstract
(2) There were rather large heat exchanges between the "mixing vessel" and the "reference vessel" caused by conduction along the thermopile between the two vessels. (3) There was necessarily a heat effect due to breaking the glass seal which initially separated the two liquids. This effect was usually small but since no two seals were identical it was not reproducible. (4) The quantity of mercury in the calorimeter (about 350 g), and hence the heat capacity (about 50 JrC), were larger than desirable. These disadvantages have been largely overcome in the new calorimeter described below. In particular:Keywords
This publication has 5 references indexed in Scilit:
- A comparative study of thermodynamic properties and molecular interactions in mono- and polychloroalkane + n-alkane or + cyclohexane mixturesFluid Phase Equilibria, 1988
- Excess enthalpies from displacement calorimetry excess enthalpies for 1,1,1- trichloroethane+carbon tetrachloride and 2-chloro-2-methylpropane+carbon tetrachloride at 298.15 KThe Journal of Chemical Thermodynamics, 1979
- Vapour pressures and excess Gibbs energy of the liquid mixture carbon tetrachloride + 1,1,1-trichloroethaneThe Journal of Chemical Thermodynamics, 1976
- The excess enthalpies of cyclohexane + n-dodecane and + n-nonaneThe Journal of Chemical Thermodynamics, 1976
- Construction of an adiabatic calorimeter. Thermodynamic properties of standard n-heptane from 155 to 270 K and of 2,2-dichloropropane from 135 to 270 KThe Journal of Chemical Thermodynamics, 1972