Empirical Considerations of Entropy. I. The Entropies of the Oxy-Anions and Related Species
- 1 September 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (9), 1443-1446
- https://doi.org/10.1063/1.1699276
Abstract
The partial molal entropies for oxy‐anions and related species have been correlated as a function of the charge, interatomic distance, and certain structural factors. An equation is given by which the entropy for unknown species can now be estimated fairly accurately. In the few cases where the method does not give good agreement, the data are open to suspicion as indicated by other independent observations. Some applications and extensions of the method are indicated for future study.Keywords
This publication has 8 references indexed in Scilit:
- Interatomic Distances and Bond Character in the Oxygen Acids and Related SubstancesThe Journal of Physical Chemistry, 1952
- The Entropy of Aqueous SolutesThe Journal of Chemical Physics, 1951
- Ionization and Hydration Equilibria of Periodic Acid1Journal of the American Chemical Society, 1951
- Some Revisions of the Covalent Radii and the Additivity Rule for the Lengths of Partially Ionic Single Covalent Bonds*Journal of the American Chemical Society, 1941
- Oxygen Exchange between Anions and WaterJournal of the American Chemical Society, 1940
- The Heat of Solution of Gadolinium Sulfate Octahydrate and the Entropy of Gadolinium IonJournal of the American Chemical Society, 1940
- The Heats of Ionization of Water, Ammonium Hydroxide, Carbonic, Phosphoric, and Sulfuric Acids. The Variation of Ionization Constants with Temperature and the Entropy Change with IonizationJournal of the American Chemical Society, 1937
- Volumen und Hydratationswärme der IonenThe European Physical Journal A, 1920