Emission spectrum of rare gas dimers in the vacuum UV regions. III. Ne2

Abstract
Emission spectra of the neon dimer have been studied in the VUV region. Liquid nitrogen cooled neon was excited with a Tesla coil or transformer discharge. Three band systems I, II, and III were observed in the 735–1000 Å range and classified as produced by electronic transitions to the common ground state X0+g(1S0) from the three low lying excited states 1u(3P2), 0+u(3P1), and 0+u(1P1), respectively. Evidence for the existence of potential humps in the lowest two upper states were observed and the hump heights were calculated to be 142±10 and 670±50 cm−1, respectively. Observations of additional spectra, a newly observed emission continuum and two diffuse band groups, are presented.