On the thermal dissociation of hydrogen

Abstract

The important role atomic hydrogen plays in the low-temperature and pressure deposition of diamond has renewed interest in the dissociation processes of hydrogen. Following a method originally developed by Langmuir and co-workers, the voltage-current characteristics of refractory filaments in vacuum and reduced-pressure gaseous environments are analyzed. Using hydrogen, deuterium, and helium, it is concluded that the difference in the power consumption by the filament in hydrogen and in vacuum is a good measure for the rate of hydrogen dissociation. This rate is shown by experiments and mathematical modeling to depend on the geometry of the refractory heater element. Relatively high dissociation rates, normalized per heater area, are obtained for small-diameter wires, and it is argued that this is indicative of a nonequilibrium dissociation process.