N,N-bis(trimethylysilyl)methoxymethlamine as a convenient synthetic equivalent for +CH2NH2: primary aminomethylation of organometallic compounds

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Abstract
The introduction of the primary aminomethyl unit at carbon through N,N-bis(trimethylsily)aminomethylation of Grignard and organolithium compounds can be achieved in good yield using N,N-bis(trimethylsily)methoxymethylamine (1).