Sn-Beta zeolite as diastereoselective water-resistant heterogeneous Lewis-acid catalyst for carbon–carbon bond formation in the intramolecular carbonyl–ene reaction
- 4 February 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 550-551
- https://doi.org/10.1039/b313738d
Abstract
The water-tolerant Lewis acid Sn-Beta isomerises citronellal to isopulegol with high diastereoselectivity working in batch or in fixed bed reactors with very high turnover numbers.Keywords
This publication has 16 references indexed in Scilit:
- Isomerisation of (+)citronellal over Zn(II) supported catalystsApplied Catalysis A: General, 2002
- Sn-MCM-41—a heterogeneous selective catalyst for the Baeyer–Villiger oxidation with hydrogen peroxideElectronic supplementary information (ESI) available: XRD pattern of as-prepared Sn-MCM-41. See http://www.rsc.org/suppdata/cc/b1/b105927k/Chemical Communications, 2001
- Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidationsNature, 2001
- Cyclisation of Citronellal to Isopulegol Catalysed by Hydrous Zirconia and Other Solid AcidsJournal of Catalysis, 2001
- Scandium trifluoromethaneslfonate, an efficient catalyst for the intermolecular carbonyl-ene reaction and the intramolecular cyclisation of citronellalTetrahedron Letters, 1998
- Novelties of eclectically engineered sulfated zirconia and carbon molecular sieve catalysts in cyclisation of citronellal to isopulegolChemical Communications, 1998
- Common Fragrance and Flavor MaterialsPublished by Wiley ,1997
- Metal cation-exchanged montmorillonite(Mn+-Mont)-catalysed carbonyl-ene reactionsJournal of the Chemical Society, Perkin Transactions 1, 1997
- Cyclization of Citronellal to Isopulegol by Zeolite CatalysisApplied Catalysis, 1989
- A Highly Stereoselective Preparation ofl-IsopulegolSynthesis, 1978